Following on from the work presented in part i, this part ii paper presents a new mathematical description for water and solute transfer in pressuredriven membrane separation processes, the. The studies on using of hybrid ix pressure driven membrane processes for prevention of membrane fouling, selective removal of targeted pollutants, treatment of waste waters and desalination of. Fundamentals of pressuredriven membrane separation. Separation of miscible liquids liquid is maintained at atmospheric pressure on the feed side of themembrane, and permeate is removed as a vapour because of a lowvapour pressure existing on the permeate side. Differs from all other membrane processes because of the phase changeof the permeate. In order to address these issues, a pumpless osmotic driven membrane and low pressure driven membrane folpm hybrid process was designed for the first time. Among all technologies available today, reverse osmosis ro is gaining worldwide. Pressure driven membrane processes are widely used in the chemical, biochemical, pharmaceutical, food and dairy industries. Electrically driven membrane processes are widely used to remove charged components from a given feed solution or suspension. Ultrafiltration uf involves pressure driven separation of materials from a feed solution. Reuse, treatment, and discharge of the concentrate of. Ultrafiltration uf is the process of separating extremely small particles and dissolved molecules.
Future research areas that need to be pursued to alleviate inorganic fouling problems in membrane installations arediscussed. Membrane technology plays a vital role in the broad range of industrial applications. Pressure driven membrane processes are widely used in downstream processing in the chemical, biochemical and food industry, and in this book i will focus on the basic theory behind pressure driven membrane processes. Plantscale engineering design of membrane processes from benchscale measurements, version 1. As follows from what has been said above, the use of pdmp is desirable for very diverse technological problems existing in pharmaceutical chemical factories and in research work, while at the present time isotropic membrane filters are mainly used in processes of fine and sterile filtration, anisotropic membranes and the corresponding equipment must be produced for the wider introduction of. In the deadend mode, one stream of the feed enters the membrane module and flows vertically toward the membrane surface, and only one stream leaves the membrane module. This process uses the reverse of the natural osmosis process. Any flux is proportional to driving force and inversely proportional to the overall resistance. To rectify this problem, it is proposed to characterize the membrane based on the pressure decay upstream from the membrane during a conventional timelag experiment, while. Use of hydrodynamic methods for pressure driven membrane operationst b b gupta ura cnrs 858,university of technology of compiegne, bp 649, compiegne, 60206, france membrane separation is one of the most used processes at present but its long term application is still. High mechanical strength is essential for pressure driven membrane separations with nanoporous singlelayer graphene, but its ability to withstand high pressures remains to be demonstrated. The use of electric current for enhancing the efficiency of.
Low pressure and energy requirements compared to ro good organic compound removal preferential removal of divalent ions over monovalent ions proper membrane selection important selection of low fouling membranes or measures to mitigate fouling selection of proper membrane and operating conditions to. Plantscale engineering design of membrane processes from. The principles of the pressure membrane processes are shown in figure 1. Comparison of membrane modules system advantages disadvantages flat sheet 1. The modes of operation of pressure driven membrane processes, concentration, diafiltration and purification, are also analysed. During the pressuredriven membrane processes of aqueous effluent containing. Membrane filters can be operated in deadend configuration, but more commonly are operated in a crossflow configuration where the pressurized feed water.
The importance of specification sheets for pressuredriven. Within one process unit, a high standard of treatment is achieved, replacing the conventional arrangement of aeration tank, settling tank and filtration that generally produces what is termed as a tertiary standard effluent. Nanofiltration is a medium to high pressure driven membrane filtration process. Negative rejections of ions in pressure driven membrane processes can be caused by several distinct mechanisms. Prior to 1980, multistage, flash distillation was the primary process. When a feed is introduced to a membrane separation system it is separated into retentate sometimes called concentrate, the fraction that is retained by the membrane, and. In these processes, the separation of a solute or dispersed matter from a liquid stream is carried out by forcing the liquid through the membrane, using a pressure difference as the driving force. Shift from a thermally driven processes to a more economical, pressure driven process for desalination. Ultrafiltration is also a membrane separation process driven by pressure. The driving force for pressure driven processes is pressure difference. Basics of membrane technology viatcheslav freger wolfson department of chemical engineering thitechnion ilisrael itittinstitute of th ltechnology, hifhaifa, ilisrael zero liquid discharge workshop, gandhinagar, january 27. Applications of membrane processes to the downstream processing of biological products are presented, namely cell harvesting by micrifiltration, protein transmission and recovery from whole fermentation broths and cell.
The feed flow through the membrane tube has an elevated pressure as driving force for the filtration process and a high flow speed to create turbulent conditions. Microfiltration is a low pressure driven membrane filtration process, which is based on a membrane with an open structure allowing dissolved components to pass while most nondissolved components are rejected by the membrane. In this chapter first the stateoftheart of conventional membranes for pressure driven processes reverseosmosis, nanofiltration, ultrafiltration and gas separation will be summarized, taking. Membrane processes for water and wastewater treatment tel. Membrane filtration rochester institute of technology. In order to establish an electrical driving force you need an electrical field. Flux, transmembrane pressure, osmotic pressure, osmotic pressure model, resistance towards mass transport, concentration polarization, gel layer model, and membrane fouling are all important terms that are explained and described. As follows from what has been said above, the use of pdmp is desirable for very diverse technological problems existing in pharmaceutical chemical factories and in research work, while at the present time isotropic membrane filters are mainly used in processes of fine and sterile filtration, anisotropic membranes and the corresponding equipment must be. Pressure driven membrane processes have become a wellestablished technology in many industrial applications. But improvements in membrane technology have made them an increasingly popular choice for removing microorganisms, particulates, and natural organic materials that foul waters taste and taint its clarity.
Thus the applied driving force is a voltage difference and the components that are removed are ions. Pressure driven membrane processes are widely used in almost all kinds of chemical, pharmaceutical, food and dairy industries. Its main difference from reverse osmosis is the type of membrane used. This size range allows for the concentration of high molecular weight proteins, macromolecules, and other small, suspended solids. Membrane separation processes have several advantages.
The pressure driven membrane processes are also used in forward osmosis applications, where they are used for draw solution recovery. Pressure driven membranes have been classified into four categories based on the membrane rejection properties as follows. All processes except electrodialysis are pressure driven. In contrast to pressure driven membrane processes where you have a volume flux through the membrane, you have a flux of ions through the membrane in electrically driven membrane processes. Pressure driven membrane processes include microfiltration, ultrafiltration, nanofiltration and reverse osmosis. Membrane separation processes 1 dialysishemodialysis electrodialysis reverse osmosis. In a number of cases, in a final count, the phenomenon is brought about by increased. While reverse osmosis membranes are nonporous and therefore, permeable only to very small molecules, ultrafiltration membranes are microporous and permeable to small solute species in addition to the solvent. New concept of pumpless forward osmosis fo and low. Membrane filtration an overview sciencedirect topics. Membranes are thin films of synthetic organic or inorganic ceramic materials, which can bring about a very selective separation between a fluid and its components. Microfiltration mf membranes have the largest pore size 0. Actually pressure driven membrane processes can be operated in two different modes.
Membrane technology covers all engineering approaches for the transport of substances between two fractions with the help of permeable membranes. Hybrid ion exchange pressure driven membrane processes. The most important feature of a membrane is the semipermeability different membrane separation processes based on different molecular properties like size, vapour pressure, affinity, charge and chemical nature it must have high permeability for some species and low permeability for others. Ro is a pressuredriven membrane separation process to remove most of the dissolved contaminants from water. May 07, 20 separation of miscible liquids liquid is maintained at atmospheric pressure on the feed side of themembrane, and permeate is removed as a vapour because of a lowvapour pressure existing on the permeate side. In this text we will focus on the pressure driven membrane processes, in which the flux through the membrane is induced by a hydrostatic pressure difference between the bulk solution and the permeate side. Inorganic fouling of pressuredriven membrane processes. The pressure membrane processes are used to concentrate or refine diluted solutions and dispersions. The membranes used in this process are commonly tubes with a membrane layer on the inside wall of the tube. Negative rejection of ions in pressuredriven membrane processes. The picture shows a pilot of bluetec, in which ro and md can be applied after fo. Fundamentals of pressuredriven membrane separation processes this chapter presents some basic concepts related to. Machine dimensions are cited from the manual operation guide for sepa. Mf and uf are pressure driven membrane processes that use microporous membranes to remove particulate matter including turbidity and microorganisms, via a sieving mechanism, on the basis of size exclusion.
Comparison of membrane processes 2 microfiltration mf microfiltration removes particles in the range of approximately 0. Membrane processes widely studied as a means of desalting brackish or seawater. Fundamentals of pressuredriven membrane separation processes. Advanced polymeric and organicinorganic membranes for. Effects of operating parameters and membrane properties on the formation of inorganic scale at the membrane surface are also evaluated. The associated effects depend on the system being separated, the membrane structure, the nature of the electric field d. Application of pressure driven membrane processes microfiltration, ultrafiltration, nanofiltration, and reverse osmosis results in the generation of a large concentrated waste stream, the concentrate fraction, as a byproduct of the purification process. Membrane processes do not require heating, which makes the process suitable for the treatment of thermolabile products. Gas separation across a membrane is a pressure driven process, where the driving force is the difference in pressure between inlet of raw material and outlet of product. Driving forces in membrane processes force process species passing through membrane species not passing through membrane hydrostatic pressure reverse osmosis ultrafiltration solvent solvent and small solutes ionic solutes tc cations. Isodis 204685en, guidelines for performance evaluation of. Membrane water treatment systems were originally used only in desalination projects. The membrane used in the process is a generally nonporous layer, so there will not be a severe leakage of gas through the membrane. Membrane characterization based on the upstream pressure.
An algorithm of any membrane process is a set of linked submodels describing mass and energy fluxes in both liquid phases and across membrane. Separation of organic solutes by membrane pressuredriven. We monitored failure of centimeterscale singlelayer graphene membranes on porous supports subjected to high pressures. Membrane processes a membrane process is a kinetics. These two processes do not remove ions or other dissolved constituents. Within the family of pressure driven membrane processes, ultrafiltration uf lies between microfiltration and nanofiltration in terms of pore size, which can range from 1100 nm. It has been noted that fo is less likely to foul and less complicated than pressure driven membrane processes like ro 23, 32. Different membrane separation processes based on different molecular properties like size, vapour pressure, affinity, charge and chemical nature it must have high permeability for some species and low permeability for others the membrane filtration can be seen as an alternative to flocculation, sedimentation, adsorption, extraction or. Pressure driven membrane processes 4 1 introduction pressure driven membrane processes are widely used in almost all kinds of chemical, pharmaceutical, food and dairy industries. Even though membrane processes are a relatively new type of separation technology, several membrane processes, particularly pressure driven membrane processes including reverse osmosis ro, nanofiltration nf, ultrafiltration uf, and microfiltration mf, are already applied on an industrial scale to food and bioproduct processing. In the dairy industry, microfiltration is widely used for bacteria reduction. All types of fouling biofouling, organic, colloidal, and scaling can be damaging.
Reuse, treatment, and discharge of the concentrate of pressure. Divalent ions are to a large extent rejected by the membrane. Safe drinking water is essential membrane processes. Pdf reuse, treatment, and discharge of the concentrate. Transport of mass and mechanical energy can be expresses as follows. In contrast to pressure driven membrane processes where you have a volume flux through the membrane. Application of pressuredriven membrane processes microfiltration. Thus the term dxdx in equation 1 can be replaced by p which is the difference between the pressure of the bulk side and the permeate side. Ps prozesstechnik gmbh neuhausstrasse 36 tel 41 61 544 3003 ch4057 basel email.
History and current status of membrane processes for. Itrc pressuredriven membrane separation technology. Research on forward osmosis membrane technology still needs. Regardless of the membrane system, biofouling is a longterm problem. This is because applied hydraulic pressure causes compact. Comparison of membrane processes applied membranes, inc. History and current status of membrane desalination process. The driving force in pressuredriven membrane separation is of course the pressure, or the pressure difference between the upstream and the downstream of the membrane, or between the feed and the permeate. Can be defined as a pressure driven membrane process that can be used in separation and concentration of substances having a molecular weight between 103 106 daltons most widely used in dairy industry. Pdf mass transfer in pressuredriven membrane separation. Microfiltration and ultrafiltration is widely used in food and beverage processing beer microfiltration, apple juice ultrafiltration, biotechnological applications and pharmaceutical industry antibiotic production, protein purification, water purification and wastewater treatment, the microelectronics industry, and. The core in every membrane process is, thus, the membrane that allows certain. In general, suspended particles and large colloids are rejected while macromolecules and dissolved solids pass through the mf membrane.
Pressure driven membrane processes the pressure driven membrane processes include microfiltration mf, ultrafiltration uf, nanofiltration nf, and reverse osmosis ro. Membrane processes a membrane is a selective barrier that permits the separation of certain species in a fluid by combination of sieving and diffusion mechanisms the membrane is a synthetic material that is semipermeable. The size of separated particles or molecules and chemical properties of the solvent are critical in the selection of the appropriate membrane type. Membrane bioreactors mbrs combine the use of biological processes and membrane technology to treat wastewater. In addition the relatively low capital and operating costs involved make membrane processes an appealing alternative to more conventional separation processes, particularly when dealing with dilute solutions. Aug 02, 2003 application of pressure driven membrane processes microfiltration, ultrafiltration, nanofiltration, and reverse osmosis results in the generation of a large concentrated waste stream, the concentrate fraction, as a byproduct of the purification process. In general, mechanical separation processes for separating gaseous or liquid streams use membrane technology.
In forward osmosis the feedwater solution becomes more concentrated on one side of the membrane and the draw solution becomes more diluted at the other, this effectively reduces the differential osmotic pressure and therefore the solvent flow. Schematic diagram of a system combining fo and pressuredriven membrane processes the pressuredriven membrane process includes ro, nf, uf, and. Membrane processes reverse osmosis ultrafiltration microfiltration what are membranes. Membrane filtration mf is a pressure driven separation process that employs a membrane for both mechanical and chemical sieving of particles and macromolecules benjamin and lawler, 20. Separation of organic solutes by membrane pressuredriven processes. Membrane separation processes membrane separation consists of different process operating on a variety of physical principles and applicable to a wide range of separations of miscible components these methods yield only a more concentrated liquid stream than feed.
The most extensively used membrane material is cellulose acetate though an aromatic polyamide is also used. The technology is used to remove particulate and microbial contaminants, but it does not remove ions. The available pdms processes are primarily distinguished from each other in terms of the molecular size of the contaminants of solutes that they will remove. The pressure applied in the ro process is influenced by the concentration of solute at the feed. The transport of substances through a membrane and its separation properties change significantly when pressure driven membrane processes are carried out in an electric field ref. I membrane separation technologies takeshi matsuura encyclopedia of life support systems eolss membrane separation technologies takeshi matsuura department of chemical engineering, university of ottawa, ottawa, ont. Review article membrane separations in dairy processing.
A membrane process is capable of performing a certain separation by use of a membrane. The concept of membrane processes is relatively simple but nevertheless often unknown. Singlelayer graphene membranes withstand ultrahigh. Fo is a membranebased separation process driven by the osmotic pressure difference between the two sides of the membrane. Pressuredriven membrane process an overview sciencedirect.
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